Calculate ΔS(for the system) when the state of 2.00 mol diatomic perfect gas molecules, for which Cp, m (7/2)R, is changed from 25 C and 1.50 atm to 135 C and 7.00 atm. How do you rationalize the sign of ΔS?

answer: the value of enthalpy change will be -152.80 kj.

solution:

pressure = 1atm , temperature = = 298 k

given that pressure and temperature are same in both gases , the number of moles of both gases can be determined by the ideal gas equation.

according to reaction 3 moles no are reacting with 1 mol of ,then 0.49 mol of no will react with moles of ozone that is 0.16 moles of ozone. since, no is limiting reagent and is an excessive reagent.

enthalpy change for the reaction between the given volumes of the gases is :

answerambulatory;