A. Rank the following substances in order of decreasing standard molar entropy (S∘). Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
Br(g)
Cl2(g)
I2(g)
F2(g)
B. Rank the following substances in order of decreasing standard molar entropy (S∘).
Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
H2S(g)
H2O(g)
H2O2(g)
C. Rank the following substances in order of decreasing standard molar entropy (S∘).
Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.
C(s, amorphous)
C(s, diamond)
C(s, graphite)

A. Rank the following substances in order of decreasing standard molar entropy (S∘).

Rank the gases from largest to smallest standard molar entropy

I2(g)>Br2(g)>Cl2(g)>F2(g)

B. Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.

H2O2(g)>H2S(g) >H2O(g)

C. Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.

C(s, amorphous) >C(s, graphite)>C(s, diamond)

Explanation:

Hello,

In this case, we can apply the following principles to explain the order:

- The greater the molar mass, the larger the standard molar entropy.

- The greater the molar mass and the structural complexity, the larger the standard molar entropy.

- The greater the structural complexity, the larger the standard molar entropy.

A. Rank the following substances in order of decreasing standard molar entropy (S∘).

Rank the gases from largest to smallest standard molar entropy

I2(g)>Br2(g)>Cl2(g)>F2(g)

This is due to the fact that the greater the molar mass, the larger the standard molar entropy.

B. Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.

H2O2(g)>H2S(g) >H2O(g)

This is due to the fact that the greater the molar mass and the structural complexity, the larger the standard molar entropy as the hydrogen peroxide has four bonds and weights 34 g/mol as well as hydrogen sulfide that has two bonds only.

C. Rank the gases from largest to smallest standard molar entropy. To rank items as equivalent, overlap them.

C(s, amorphous) >C(s, graphite)>C(s, diamond)

Since the molecular complexity is greater in the amorphous carbon (messy arrangement), mid in the graphite and lower in the diamond (well organized).

Regards.

first, consult an activity series chart to determine if al is more reactive than fe. it is, so it will replace the fe. now, one can continue with the problem.

next, make sure you have a correctly balanced equation.

3feo + 2al ==> 3fe + al2o3

now, determine which reactant (feo or al) is in limiting supply.

moles feo present = 125 g x 1 mole/71.8 g = 1.74 moles

moles al present = 25.0 g x 1 mole/26.98 g = 0.927 moles

since from the balanced equation, it take 3 mol feo for every 2 mol al, al will be limiting.

you can determine this simply by dividing moles of each by their coefficient in the balanced equation. for example: 1.74/3 = 0.58 and 0.927/2 = 0.464. al is less, so it is limiting.

finally, using the stoichiometry in the balanced eq. determine mass of fe that can be produced from 0.927 moles of al.

0.927 moles al x 3 moles fe/2 moles al x 55.8 g/mole = 77.6 g

the volume increases