As an atom's nucleus gets larger the electric charges repelling the protons get larger. To compensate for this greater
electric charge the atom
needs more neutrons to gain enough nuclear binding forces to overcome
the repulsion
needs fewer neutrons to gain enough nuclear binding forces to overcome
the repulsion.
needs more electrons to gain enough nuclear binding forces to overcome
the repulsion.
Eliminate
needs fewer electrons to gain enough nuclear binding forces to overcome
the repulsion

hydrocarbons are organic compounds that contain only hydrogens and carbons. they can be saturated (those which contain only carbon-carbon single bonds) or unsaturated (those which contain carbon-carbon double or triple bonds) in nature. hydrocarbons can undergo several reactions like substitution, elimination etc.  

on substituting one or more hydrogen atoms in hydrocarbon it results in the formation of haloalkane. as the halogen atoms are large compared to the carbon and hydrogen atoms, due to which the molecular weight increases and the bond become polar because of presence electronegative halogen atom and results in the increase in boiling point of the haloalkane.

thus, the correct option is (b) that is the boiling point of the new compound increases on substituting a hydrogen atom with a halogen in a hydrocarbon.