The normal boiling point of a substance is defined to be the temperature at which the liquid phase of the substance is in equilibrium with the gas phase at 1 atm pressure. The normal boiling point of methanol is 80oC and ∆H vap = 38 kJ/mol. What is the ∆Scrap value

ΔSv = 0.1075 KJ/mol.K

Explanation:

Binary solution:

∴ a: solvent

∴ b: solute

in equilibrium:

⇒ Ln (1 - Xb) = ΔG/RT

∴ ΔG = ΔHv - TΔSv

⇒ Ln(1 -Xb) = ΔHv/RT - ΔSv/R

∴ Xb → 0:

⇒ Ln(1) = ΔHv/RT - ΔSv/R

∴ T = T*bnormal boiling point

⇒ 0 = ΔHv/RT*b - ΔSv/R

⇒ ΔSv = (R)(ΔHv/RT*b)

⇒ ΔSv = ΔHv/T*b

∴ T*b = 80°C ≅ 353 K

⇒ ΔSv = (38 KJ/mol)/(353 K)

⇒ ΔSv = 0.1075 KJ/mol.K

atomic number of carbon is 6

electronic configuration of carbon is 1s²2s²2p²

orbital diagram of carbon is as shown here in the image.