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Chemistry, 10.04.2020 04:59 angelinaviera09

The decomposition of nitramide, O 2 NNH 2 , O2NNH2, in water has the chemical equation and rate law O 2 NNH 2 ( aq ) โŸถ N 2 O ( g ) + H 2 O ( l ) rate = k [ O 2 NNH 2 ] [ H + ] O2NNH2(aq)โŸถN2O(g)+H2O(l)rate=k[O2NN H2][H+] A proposed mechanism for this reaction is O 2 NNH 2 ( aq ) k 1 โ‡Œ k โˆ’ 1 O 2 NNH โˆ’ ( aq ) + H + ( aq ) ( fast equilibrium ) O2NNH2(aq)โ‡Œkโˆ’1k1O2NNHโˆ’(aq)+H+(aq)(f ast equilibrium) O 2 NNH โˆ’ ( aq ) k 2 โˆ’โ†’ N 2 O ( g ) + OH โˆ’ ( aq ) ( slow ) O2NNHโˆ’(aq)โ†’k2N2O(g)+OHโˆ’(aq)(slow) H + ( aq ) + OH โˆ’ ( aq ) k 3 โˆ’โ†’ H 2 O ( l ) ( fast ) H+(aq)+OHโˆ’(aq)โ†’k3H2O(l)(fast) What is the relationship between the observed value of k k and the rate constants for the individual steps of the mechaanism?

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