Complete all of the calculations for creating a calibration curve that you will use to determine the concentration of an unknown sample in lab this week. The stock solution is 300 ppm quinine. First determine the dilution to create a25-mL solution of 1 ppm quinine solution. Then use that 1 ppm stock solution to prepare five standard solutions of quinine, 25 mL each. You can choose your concentration range but keep the max below 0.2 ppm

here we have to get the change of moles on decrease the volume of the reaction in gas phase.

the   per the given options it will decrease by (d) 11-50%

we know, on decreasing the volume of the gas phase reaction the reaction moves to the product side.

the reaction:                     so₂cl₂ (g) = so₂ (g) + cl₂ (g)         total

the moles at equilibrium:   1 - α                 α               α           = 1+α

concentrations:                   1 - α               α               α           = 1 + α

(concentration = moles/volume, as volume is 1 l)

(where α is the degree of dissociation)

now the dissociation constant in terms of concentration is :

=  

or,

or,   = (at v = 1l)

the reaction:                     so₂cl₂ (g) = so₂ (g) + cl₂ (g)         total

the moles at equilibrium:   1 - α                 α               α           = 1+α

concentrations:               (1 - α)/0.5           α/0.5         α/0.5       = (1 + α)/0.5

thus, the dissociation constant in terms of concentration is :

or,  

=  

so, the change of 1 : 1/0.5

or, 1: 2

thus it will decrease by 50%.

or, as per the given options it will decrease by 11-50%

each chemical family is represented as a group or column on the periodic table. based on chemical properties, there are 6 types of chemical families. group 1 represents alkali metals, group 2 represents alkaline earth metals, groups 3 to 12 represent transition metals, groups 13 to 16 represent non-metals and other metals, group 17 represents halogens and group 18 represents noble gases.