The emission spectrum of hydrogen shows discrete, bright, colored lines. Which characteristic of the Bohr model is best supported by this observation?
Energy is released when an electron moves to a higher energy level.
Smaller atoms have fewer spectral lines than larger atoms.
The energy of an electron increases with distance from the nucleus.
Electrons cannot exist in locations other than in specific orbits.

i don't know people like to fight everywhere rip.

hydrocarbons are organic compounds that contain only hydrogens and carbons. they can be saturated (those which contain only carbon-carbon single bonds) or unsaturated (those which contain carbon-carbon double or triple bonds) in nature. hydrocarbons can undergo several reactions like substitution, elimination etc.  

on substituting one or more hydrogen atoms in hydrocarbon it results in the formation of haloalkane. as the halogen atoms are large compared to the carbon and hydrogen atoms, due to which the molecular weight increases and the bond become polar because of presence electronegative halogen atom and results in the increase in boiling point of the haloalkane.

thus, the correct option is (b) that is the boiling point of the new compound increases on substituting a hydrogen atom with a halogen in a hydrocarbon.