Benzene was treated with a set of unknown reagents. Using the spectral data below, draw the most likely product and select the most likely set of reagents. 1H NMR: See spectra below. 13C NMR: 142 ppm, 128 ppm, 128 ppm, 125 ppm, 38 ppm, 24 ppm, and 13 ppm. MS: There is no detectable M+2 peak. IR: Peaks observed at 3100 cm-1 and at 2900 cm-1. There is NO absorbance near 1700 cm-1.

Tooth enamel consists mainly of the mineral calcium hydroxyapatite, ca_10(po_4)_6(oh)_2. trace elements in teeth of archaeological specimens provide anthropologist with clues about diet and diseases of ancient people. students at hamline university measured strontium in enamel from extracted wisdom teeth by atomic absorption spectroscopy. solutions with a constant total volume of 10.0 ml contained 0.726 mg of dissolved tooth enamel plus variable concentrations of added sr. added sr find the concentration of sr in the 10 ml sample solution in parts per billion = ng/ml. find the concentration of sr in tooth enamel in parts per million = mu g/g.