Why do the coefficients of an elementary step equal the reaction orders of its rate law, but those of an overall reaction do not? This is generally not true, the coefficients cannot be used for the reaction orders of its rate law for either type of reaction. An elementary step uses an average reaction rate calculation while the overall reaction uses an instantaneous rate calculation. Overall reactions are always in dynamic equilibrium while elementary steps are not. An elementary step is a single molecular event and occurs in one step, but the overall reaction is generally a series of elementary steps which are not necessarily proportional to the product of the overall reaction concentrations.

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sulfur belongs to group 16 because it can be found in nature whether it is in a free or combined state.

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assuming that your periodic table has eighteen columns, you should highlight   the four elements in the third column from the left of the table.

neutral atoms of elements after calcium contain d electrons. the energy of d orbitals of a particular main shell lies between the energy of the s and p orbitals of the next main shell. for example, electrons in the have energy higher than those in the orbital while lower than those of the orbital.

by the aufbau principle, electrons fill orbitals one at a time, starting from those of the lowest energy. the orbital is therefore filled right after orbitals and before orbitals.  

potassium has electron configuration and calcium . the s orbital of a main shell holds a maximum of two electrons. the next element would thus have the electron configuration and satisfy the requirements.

a neutral atom of the element contains three electrons on top of the most recent noble gas element. it should thus be placed in the third column of the periodic table. both scandium and yttrium would satisfy the conditions. an aufbau diagram indicates that the 4f orbital is filled before the 5d. however, it appears that exceptions exists for both lanthanum and actinium. neutral atoms of the two d-block elements also demonstrate the and should be highlighted as well.