The absolute pressure within a 35.0-liter gas cylinder should not exceed 51.0 atm. Suppose the cylinder contains 50.0 mol of a gas. Use the SRK equation of state to calculate the maximum permissible cylinder temperature if the gas is (a) carbon dioxide and (b) argon. Finally, calculate the values that would be predicted by the ideal-gas equation of state

Answerthis solution will not form a precipitateexplanationsolubility equilbrium:         pbf₂(s)  ⇄ pb²⁺(aq) + 2 f⁻(aq)the solubility product expression is    (we exclude solids from the equilibrium expression).now suppose we have the trial ion product q, which we can define as    then, we can interpret  q as the product of the concentration of the ions that we have and ksp as the product of the ion concentrations that are needed to form a saturated solution.if q > ksp, then that implies that there will be a surplus of ions that exceed the amount that is required to form a saturated solution. a precipitate will then form (the precipitate continually  forms until the surplus ions are removed and q is decreased to ksp's value).if q = ksp, the saturated solution that forms is barely saturated and the precipitate will be minimal.if q < ksp, then the ion concentration will not be enough to form a saturated solution (so no precipitate).using our information, we calculate the trial ion product:     since q = 2.7  × 10⁻⁸ < ksp =  4  ×  10⁻⁸, a precipitate will not form.

Answerδh > 0explanationc₆h₆  (s)  → c₆h₆ (l)if you are changing it from a solid to a liquid, you are pretty much melting the solid. this requires heat energy. therefore, the reaction is endothermic (takes in energy); the system enthalpy increases as the reaction proceeds: δh > 0.