Chemistry, 11.02.2020 02:58 derrishamckenzie22

Given the data calculated in Parts A, B, C, and D, determine the initial rate for a reaction that starts with 0.45 M of reagent A and 0.90 M of reagents B and C?

Trial [A]

(M) [B]

(M) [C]

(M) Initial rate

(M/s)

1 0.20 0.20 0.20 6.0×10−5

2 0.20 0.20 0.60 1.8×10−4

3 0.40 0.20 0.20 2.4×10−4

4 0.40 0.40 0.20 2.4×10−4

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Answers

Answer from: nxusasmangaliso8780

$\large\boxed{\large\boxed{0.0014M/s}}$

Explanation:

From the table, first find the order of reaction, then find the rate constant, write the rate equation, and, finally, subsititue the data for the reaction that starts with 0.45M of reagent A and 0.90 M of reagents B and C.

1. Table

Trial [A] (M) [B] (M) [C] (M) Initial rate (M/s)

1 0.20 0.20 0.20 6.0×10⁻⁵

2 0.20 0.20 0.60 1.8×10⁻⁴

3 0.40 0.20 0.20 2.4×10⁻⁴

4 0.40 0.40 0.20 2.4×10⁻⁴

2. Orders

a) From trials 3 and 4 you learn that the initial concentration of B does not change the change teh rate of the reaction. Hence the order with respect to [B] is 0.

b) From trials 1 and 2 you learn that when the concentration of C is tripled the rate of reaction is also tripled:

0.60 / 0.2 = 3, and1.8×10⁻⁴ / 6.0×10⁻⁵ = 3

Hence, the order with respect to C is 1.

c) From trials 1 and 3 you get:

0.40/0.2 = 22.4×10⁻⁴ / 6.0×10⁻⁵ = 4

Which means that when the concentration of A is doubled, the rate of the reaction is quadruplicated. Hence, the order of the reaction with respect to A is 2.

3. Rate equation

Ther orders are:

$a=2\\\\b=0\\\\c=1$

Hence the rate is:

$rate=k[A]^a{B}^b[C]^c\\ \\ rate=k[A]^2[B]^0[C]^1=k[A]^2C$

4. Rate constant, k

You can use any trial to find the value of the constant, k

Using trial 1:

$6.0\times 10^{-5}M/s=k(0.20M)^2(0.20M)\\ \\ k=\frac{6.0\times 10^{-5}M/s}{(0.20M)^2(0.20M)}=0.0075M^{-2}s^{-1}$

5. Rate law:

rate=k[A]^2C=0.0075[A]^2[C]

6. Substitute

Subsititue the data for the reaction that starts with 0.45M of reagent A and 0.90 M of reagents B and C.

$rate=0.0075M^{-2}s^{-1}[A]^2[C]=0.0075M^{-2}s^{-1}[0.45M]^2[0.9M]$

$r=0.00136688M/s\approx 0.0014M/s$

Answer from: Quest

2.00 is the !

Answer from: Quest

the correct answer is b. a strong acid completely dissociates to its ions when dissolved in water. $hbr$ completely dissociates to $h^+$ and $br-$ ions. a is incorrect because $h_2s$ does not fully ionize to $h^+$ and $hs^-$ ions and some remain as the compound $h_2s$ . c and d are incorrect because, $li_2o$ and $libr$ do not fall into the category of bronsted lowry acids. a bronsted lowry acid is a proton donor and since both molecules do not have a proton to donate they are not bronsted lowry acids. likewise, if we use the lewis acid definition, they cannot be acids. a lewis acid is an electron pair acceptor. both $li_2o$ and $libr$ have a complete octet so can not accept any electrons which disqualifies them as acids.

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