A49.48-ml sample of an ammonia solution is analyzed by titration with hcl. it took 38.73 ml of 0.0952 m hcl to titrate the ammonia. what is the concentration of the original ammonia solution?

M₂ = 0.0745 M

Explanation:

In case of titration , the following formula can be used -

M₁V₁ = M₂V₂

where ,

M₁ = concentration of acid ,

V₁ = volume of acid ,

M₂ = concentration of base,

V₂ = volume of base .

from , the question ,

M₁ = 0.0952 M

V₁ = 38.73 mL

M₂ = ?

V₂ = 49.48 mL

Using the above formula , the molarity of ammonia , can be calculated as ,

M₁V₁ = M₂V₂  

0.0952 M * 38.73 mL = M₂* 49.48 mL

M₂ = 0.0745 M

when 25.0 ml of 0.700 mol/l naoh was mixed in a calorimeter with 25.0 ml of 0.700 mol/l hcl, both initially at 20.0 °c, the temperature increased to 22.1 °c. the heat capacity of the calorimeter is 279 j/°c.

the equation for the reaction is:

naoh + hcl → nacl + h₂o

moles of hcl = 0.0250 l hcl ×

0.700

mol hcl

1 l hcl = 0.0175 mol hcl

volume of solution = (25.0 + 25.0) ml = 50.0 ml

mass of solution = 50.0 ml soln ×

1.00

ml soln

= 50.0 g soln

δt=t2-t1

= (22.1 – 20.0) °c = 2.1 °c

the heats involved are

heat from neutralization + heat to warm solution + heat to warm calorimeter = 0

q1+q2+q3=0

nδh+mcδt+cδt=0

0.0175 mol ×

δh

+ 50.0 g × 4.184 j·g⁻¹°c⁻¹ × 2.1 °c + 279 j°c⁻¹ × 2.1 °c = 0

0.0175 mol ×

δh

+ 439.32 j + 585.9 j = 0

0.0175 mol ×

δh

= -1025.22 j

δh=1025.22j0.0175 mol= -58 600 j/mol = -58.6 kj/mol

20 drops hope this