The ph of a 0.65m solution of hydrofluoric acid hf is measured to be 1.68. calculate the acid dissociation constant ka of hydrofluoric acid. round your answer to 2 significant digits.

Kₐ = 6.7 x 10⁻⁴

Explanation:

First lets write the equilibrium expression, Ka , for the dissociation of hydrofluoric acid:

HF + H₂O     ⇄   H₃O⁺ +   F⁻

Kₐ = [ H₃O⁺ ] [ F⁻ ] /[ [ HF ]

Since we are given the pH we can calculate the  [ H₃O⁺ ]  ( pH = - log [ H₃O⁺ ] , and because the acid dissociates into a 1: 1  relation , we will also have [F⁻ ]. The  [ HF ] is given in the question so we have all the information that is needed to  compute Kₐ.

pH = -log [ H₃O⁺ ]

1.68 = - log [ H₃O⁺ ]

Taking antilog to both sides of this equation:

10^-1.68 = [ H₃O⁺ ] ⇒ 2.1 X 10⁻²  M= [ H₃O⁺ ]

[ F⁻ ] = 2.1 X 10⁻² M

Solving for Kₐ :

Kₐ = ( 2.1 X 10⁻² ) x  ( 2.1 X 10⁻² ) / 0.65 = 6.7 x 10⁻⁴  

(Rounded to two significant figures, the powers of 10 have infinite precision )

given:

mass of na = 115 g

excess cl2

to determine:

mass of nacl produced

explanation:

given reaction is-

2na(s) + cl2(g) → 2nacl(s)

since cl2 is in excess, na will be the limiting reagent

as per the reaction stoichiometry na: nacl = 1: 1

i.e. moles of na reacted = moles of nacl formed

now, # moles of na = mass of na/atomic mass

                                  = 115 g/23 g.mol-1 = 5 moles

therefore, moles of nacl = 5

molar mass of nacl = 58 g/mol

mass of nacl = 5 moles * 58 g.mol-1 = 290 g

ans: amount of nacl produced = 290 g

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