How do you correlate spectrochemical series with the pi bonding ability of ligands?

Achemistry student weighs out of phosphoric acid , a triprotic acid, into a volumetric flask and dilutes to the mark with distilled water. he plans to titrate the acid with solution. calculate the volume of solution the student will need to add to reach the final equivalence point. round your answer to significant digits.

Using a value of ksp = 1.8 x 10-2 for the reaction pbcl2 pb+2(aq) + 2cl -(aq). if the value of ksp was determined to be only 1.2 x 10-2: too much solid has dissolved. additional precipitate is forming. the solution is unsaturated. the ions are now combining to reduce their concentrations.

What is the solubility of substance?