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Chemistry, 27.11.2019 23:31 alex1975

Measuring the approximate mass of an ion without using a standard can be accomplished via the following variant of the peak-matching technique describe in the problem 5. the peakmatching technique is used to alternately cause the p+ ion and the (p+1)+ ions to reach the detector. it is assumed that the difference in mass between p+ and (p+1)+ is due to a single 13c replacing a 12c atom. a) if the accelerating voltage for (p+1)+ is labeled v2 and that for p+ is v1, derive a relationship that relates the ratio v2/v1 to the mass of p+ .b) if v2/v1 =0.976542, calculate the mass of the p+ ion.

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