Chemistry, 12.11.2019 02:31 rubincain203

Write a balanced equation for the combustion of c7h16(l) (heptane) -- i. e. its reaction with o2(g) forming the products co2(g) and h2o(l). given the following standard heats of formation: δhf° of co2(g) is -393.5 kj/mol δhf° of h2o(l) is -286 kj/mol δhf° of c7h16(l) is -187.8 kj/mol what is the standard heat of reaction (δh°) for the combustion reaction of c7h16(l)? -4854.7 kj calculate the difference, δh-δe=δ(pv) for the combustion reaction of 1 mole of heptane. (assume standard state conditions and 298 k for all reactants and products.)

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Answer from: lilly4920

The standard enthalpy of reaction = -4854.7kJ

The difference: ΔH-ΔE = Δ(PV) = Δn.R.T = 9910.288 J ≈ 9.91 kJ

Explanation:

The balanced chemical equation for the combustion of heptane:

C₇H₁₆ (l) + 11 O₂ (g) → 7 CO₂ (g) + 8 H₂O (l)

Given: The standard enthalpy of formation ( $\Delta H _{f}^{\circ }$ ) for: C₇H₁₆ (l) = -187.8 kJ/mol, O₂ (g) = 0 kJ/mol, CO₂ (g) = -393.5 kJ/mol, H₂O (l) = -286 kJ/mol

To calculate the standard enthalpy of reaction ( $\Delta H _{r}^{\circ }$ ) can be calculated by the Hess's law:

$\Delta H _{r}^{\circ } = \left [\sum \nu \cdot\Delta H _{f}^{\circ }(products) \right ] - \left [\sum \nu\cdot\Delta H _{f}^{\circ }(reactants) \right ]$

Here, $\nu$ is the stoichiometric coefficient

⇒ $\Delta H _{r}^{\circ } =$

$\left [ 7\times \Delta H _{f}^{\circ }\left (CO_{2}\right )+ 8\times \Delta H _{f}^{\circ }\left (H_{2}O \right )\right ]$

$- \left [1\times \Delta H _{f}^{\circ }\left (C_{7}H_{16}\right ) +11\times \Delta H _{f}^{\circ }\left (O_{2} \right ) \right ]$

$=\left [ 7\times \left (-393.5 kJ/mol \right )+ 8\times \left (-286 kJ/mol \right )\right ]$

$-\left [1\times \left (-187.8 kJ/mol \right ) +11\times \left (0 kJ/mol \right ) \right ]$

⇒ $\Delta H _{r}^{\circ } = \left [ \left (-2754.5 \right )+ \left (-2288 \right )\right ]\left -[ \left (-187.8 \right ) +\left (0 \right )\right ]$

⇒ $\Delta H _{r}^{\circ } = \left [ -5042.5 ]\left -[ -187.8] = \left ( -4854.7kJ \right )$

To calculate the difference: ΔH-ΔE=Δ(PV)

We use the ideal gas equation: P.V = n.R.T

⇒ ΔH-ΔE=Δ(PV) = Δn.R.T

Given: Temperature:T = 298K, R = 8.314 J⋅K⁻¹⋅mol⁻¹

Δn = number of moles of gaseous products - number of moles of gaseous reactants = (7)- (11) = (-4)

⇒ ΔH-ΔE=Δ(PV) = Δn.R.T = (-4 mol) × (8.314 J⋅K⁻¹⋅mol⁻¹) × (298K) = 9910.288 J = 9.91 kJ (∵ 1 kJ = 1000J )

Answer from: Quest

2fe + 3h2so4 -> fe2(so4)3 + 3h2

it is necessary to balance equations in order to get the proper amount of reactants as well as products in order not to make a miscalculation.

you cannot change the subscripts as that would change the substance itself. for instance, diatomic elements such as h2 only have the subscript two when a gas. another example would be so4, if you were to change the subscript, the element would no longer be sulfate.

we change the coefficients instead as that only changes the number of molecules rather than the substance itself.

hope this !

Answer from: Quest

"standard molar enthalpy:

h2o ( liquid water ) : - 285.8 kj/mole

h2o ( water vapor ) : - 241.8 kj / mole.

δhrxn = - 241. 8 - ( - 285.8 )= -241.8 + 285.8 = 44.0

answer: 44.0 kj"

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Write a balanced equation for the combustion of c7h16(l) (heptane) -- i. e. its reaction with o2(g)...