4. (a) a sample of the monosaccharide (sugar) d-threose of mass 1.15 g was placed in a constant volume calorimeter and then ignited in the presence of excess oxygen. the temperature rose by 1.48°c. in a separate experiment in the same calorimeter, the combustion of 0.917 g of benzoic acid, for which the internal energy of combustion is -3226 kj/mol, gave a temperature rise of 1.94°c. calculate the enthalpy of formation of d-threose (10 pts). (b) calculate the enthalpy of formation of d-threose and benzoic acid using either an arithmetic method (e. g., bond dissociation energies) or a computational method (e. g, ab initio electronic structure computational program like molcalc. org) (10 pts). (c) compare the results from the calorimetric method used in part-a to the method used in part-b and provide a brief molecular level explanation for any potential differences (5 pts).