At 100 ∘c the equilibrium constant for the reaction cocl2(g)←→co(g)+cl2(g) has the value kc=2.19×10−10. are the following mixtures of cocl2, co, and cl2 at 100 ∘c at equilibrium? if not, indicate the direction that the reaction must proceed to achieve equilibrium.

vanderwaal's forces of attraction are the electrostatic intermolecular forces that exist in a molecule due to the temporary or permanent dipoles that are developed in a molecule. in , the major intermolecular forces are dipole-dipole interactions as the molecule is polar (bent structure). so the vanderwaal's forces of interaction in between molecules are the permanent dipole-dipole interactions that develop due to the dipole that exists in between the polar h - s bond. the positively charged hydrogen atom is attracted towards the negative end of the dipole that is sulfur of the adjacent molecule. therefore, these forces of attraction are relatively stronger than that of london dispersion forces that exist in non polar molecules.

the answer for sodium is 0.186

the answer for rubidium is 0.251