What is the definition of the fugacity coefficient for a pure component, and its condition at the ideal gas state?

For thermodynamics the fugacity (fi) of a non ideal gas is defined as the product between the activity (ai) of the gas and 1 bar of pressure.

Explanation:

For thermodynamics the fugacity (fi) of a non ideal gas is defined as the product between the activity (ai) of the gas and 1 bar of pressure.

Also, in a gas mixture the fugacity (fi) of every component of the mixture is define by a coefficient of fugacity (Фi) multiplied by the partial pressure of the gas (Pi) :

Ф

The coefficient of fugacity (Фi) is a measure of the deviation from the ideality of the gas. Thus, for an ideal gas Фi = 1 and the fugacity (fi) turns equal to partial pressure:

If Фi = 1  ⇒  

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