A35.0-ml sample of 0.20 m lioh is titrated with 0.25 m hcl. what is the ph of the solution after 23.0 ml of hcl have been added to the base?

pH = 12.33

The equation of reaction is :

LiOH(aq) + HCl(aq) --> LiCl(aq) + H2O(l)

Reactants left after the titrant is added;

Total Moles LiOH;

= 0.035L LiOH × (0.2moles/L)

= 0.007moles of LiOH

Moles of HCl;

= 0.023L HCl × (0.25moles/L)

= 0.00575moles HCl is the limiting reagent

Reacting amount of moles of LiOH;

= 0.0575 moles HCl *(1mole LiOH/1moles HCl)

=0.00575 moles LiOH (reacted)

Moles of LiOH left;

= 0.007moles total - 0.00575moles that react

= .00125 moles of LiOH (left)

LiOH is a strong base, which means that it ionizes completely.  

0.00125moles LiOH *(moles/0.058L) = 0.02155M of LiOH

LiOH(aq) --> Li+(aq) + OH-(aq)

[LiOH] = [OH-] = 0.02155 M

pOH = -log[OH-]

pOH = -log(0.02155)

pOH= 1.67

pH = 14 - pOH

pH = 14 - 1.67

pH = 12.33