Determine the freezing point of an aqueous solution containing 10.50 g of magnesium bromide in 200.0 g of water.

For an aqueous solution of MgBr2, a freezing point depression occurs due to the rules of colligative properties. Since MgBr2 is an ionic compound, it acts a strong electrolyte; thus, dissociating completely in an aqueous solution. For the equation:

                                ΔTf = (Kf)(m)(i)
where: 
ΔTf = change in freezing point = (Ti - Tf)
Ti = freezing point of pure water = 0 celsius
Tf = freezing point of water with solute = ?
Kf = freezing point depression constant = 1.86 celsius-kg/mole (for water)
m = molality of solution (mol solute/kg solvent) = ?
i = ions in solution = 3

Computing for molality:
Molar mass of MgBr2 = 184.113 g/mol

m = 10.5g MgBr2 / 184.113/ 0.2 kg water = 0.285 mol/kg

For the problem, 
ΔTf = (Kf)(m)(i) = 1.86(0.285)(3) = 1.59 = Ti - Tf = 0 - Tf

Tf = -1.59 celsius

The problem here is that according to aufbau principle before 3d orbital 4s subshell comes.after filling 3p orbital with electrons you have 4 electrons left, you place two in 4s with opposite spin and the other two in 3d in any of its two orbitals of total five orbitals with the same spin.

Ithink the answer is d