Neopentyl alcohol, (ch3)3cch2oh, cannot be dehydrated to an alkene without rearrangement. what is the chief product of dehydration?

Dehydration is removal of water.

In alcohols dehydration is α-β elimination or 1,2 elimination, it means the hydroxyl group will be removed from α-carbon while the hydrogen will be removed from near by carbon.

In case of neopentyl alcohol there is no β hydrogen present on the β carbon [as shown in figure].

The only possible way for it to undergo dehydration is by rearrangement.

The process or mechanism can be understood as:

so the chief product is 2-methylbut-2-ene

each  column  of the  table  is called a group. elements in a group share similar properties. groups are  read  from  top  to  bottom. metal. metalloid. nonmetal. solid. liquid. gas. fe. hg. o.  2. 3. 4. 5. 6. 7. 8. 9.  2. beryllium. 9.012. 4.  sodium. 22.990.  11. 3.  magnesium. 24.305.  12.  potassium. 39.098.  19. 4.  calcium. 40.078.  20. i guess  i  

hydrocarbons are organic compounds that contain only hydrogens and carbons. they can be saturated (those which contain only carbon-carbon single bonds) or unsaturated (those which contain carbon-carbon double or triple bonds) in nature. hydrocarbons can undergo several reactions like substitution, elimination etc.  

on substituting one or more hydrogen atoms in hydrocarbon it results in the formation of haloalkane. as the halogen atoms are large compared to the carbon and hydrogen atoms, due to which the molecular weight increases and the bond become polar because of presence electronegative halogen atom and results in the increase in boiling point of the haloalkane.

thus, the correct option is (b) that is the boiling point of the new compound increases on substituting a hydrogen atom with a halogen in a hydrocarbon.