Sawing a board in half is an example of a chemical change

Sawing a board in half is a physical change not a chemical change the board doesnt change wood or whatever material it is is still would still be wood
If it were burned it would be a chemical change but its properties stay the same atomically so thats why its not a chemical change.

c is having 4 valence electrons and is bonded to three hydrogens and one sulphur atom, therefore, the number of bond pair is equal to four. as all the valence electrons are used in forming the bonds so, there is no lone pair left on carbon.

s is having 6 valence electrons and is bonded to one other sulfur atom and one carbon atom, therefore, the number of bond pair is equal to 2. as only two valence electrons are used in forming the bonds so, four electrons are left. therefore, two lone pairs are present on s.