How is it that when a salt sample dissolves in water, the delta s for the process is positive?

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Water is highly ordered. In water each oxygen atom is connected to others around it through hydrogen bonding via bridging hydrogen atoms. When a salt like NaCl is dissolved, some of these Hydrogen bonds break.

When a salt like NaCl dissolves in water, the NaCl breaks in to ions Na+ and Cl-.

The water molecules now surround these ions.

The slightly negative oxygen end of water molecule gets near the Na+, while the slightly positive Hydrogen of water molecule gets near the Cl-.

So before salt sample dissolve, the water molecules were highly ordered due to hydrogen bonding. Now after salt dissolve there is a decrease in order and thus an increase in disorder of the water molecules.

Due to increase in disorder, entropy which is a measure of disorder increases. Since entropy increases, delta S for the process is positive.

considering the question as per the attachment

here we can see that the radon nuclide has 222 as the atomic mass number and 86 as the atomic number.

when it undergoes nuclear fission it gives polonium which has atomic mass number as 218 and atomic number will be 84 along with a helium nucleus which has 4 atomic mass number and 2 as its atomic number.

222 = 218 + 4 (atomic mass number)

86 = ? + 2; therefore ? = 86-2 = 84.

the atomic mass number of polonium will be 84.