How does man alter naturally occurring nitrogen cycle and it turn, impact other cycles on earth

Which of these statements is true about autotrophs, but not heterotrophs? a. they use sugar and oxygen to make carbon dioxide and water.b. they use chlorophyll and oxygen to make carbon dioxide and water.c. they use sunlight, water, and carbon dioxide to make sugars.d. they use sunlight, water, and oxygen to make chlorophyll.